Izakhiwo ze-Niobium
Inombolo ye-athomu | 41 |
Inombolo ye-CAS | 7440-03-1 |
Isisindo se-athomu | 92.91 |
Iphoyinti lokuncibilika | 2 468 °C |
Iphuzu elibilayo | 4 900 °C |
Ivolumu ye-athomu | 0.0180 nm3 |
Ukuminyana ku-20 °C | 8.55g/cm³ |
Isakhiwo sekristalu | cubic egxile emzimbeni |
I-lattice engaguquki | 0.3294 [nm] |
Ukuchichima koqweqwe lomhlaba | 20.0 [g/t] |
Isivinini somsindo | 3480 m/s (ku-rt)(induku ezacile) |
Ukunwetshwa kwe-thermal | 7.3 µm/(m·K) (ku-25 °C) |
I-Thermal conductivity | 53.7W/(m·K) |
Ukumelana nogesi | 152 nΩ·m (ku-20 °C) |
Mohs ubulukhuni | 6.0 |
Vickers ubulukhuni | 870-1320Mpa |
Ukuqina kweBrinell | 1735-2450Mpa |
I-Niobium, eyayaziwa ngokuthi i-columbium, iyikhemikhali enophawu Nb (owayekade eyi-Cb) kanye nenombolo ye-athomu engu-41. Iyinsimbi ethambile, empunga, ecwebezelayo, eguquguqukayo, evame ukutholakala kumaminerali i-pyrochlore ne-columbite, yingakho igama langaphambili " Columbium". Igama layo livela ezinganekwaneni zamaGreki, ikakhulukazi uNiobe, owayeyindodakazi kaTantalus, igama le-tantalum. Igama libonisa ukufana okukhulu phakathi kwalezi zakhi ezimbili emazingeni azo angokwenyama namakhemikhali, okwenza kube nzima ukuhlukanisa.
Usokhemisi oyiNgisi uCharles Hatchett wabika into entsha efana ne-tantalum ngo-1801 futhi wayiqamba ngokuthi i-columbium. Ngo-1809, usokhemisi waseNgilandi uWilliam Hyde Wollaston waphetha ngokungalungile ngokuthi i-tantalum ne-columbium ziyafana. Usokhemisi waseJalimane uHeinrich Rose wanquma ngo-1846 ukuthi i-tantalum ores iqukethe isici sesibili, asiqamba ngokuthi i-niobium. Ngo-1864 no-1865, uchungechunge lwemiphumela yesayensi lwacacisa ukuthi i-niobium ne-columbium kwakuyisici esifanayo (njengoba behlukaniswa ne-tantalum), futhi ikhulu leminyaka womabili amagama asetshenziswa ngokushintshana. I-Niobium yamukelwa ngokusemthethweni njengegama le-elementi ngo-1949, kodwa igama elithi columbium lisasetshenziswa okwamanje kwezensimbi e-United States.
Kwaze kwaba sekuqaleni kwekhulu lama-20 lapho i-niobium yaqala ukusetshenziswa khona kwezohwebo. IBrazil ingumkhiqizi ohamba phambili we-niobium ne-ferronobium, ingxubevange engu-60-70% ye-niobium enensimbi. I-Niobium isetshenziswa kakhulu kuma-alloys, ingxenye enkulu yensimbi ekhethekile njengaleyo esetshenziswa kumapayipi egesi. Nakuba lawa ma-alloys aqukethe inani eliphakeme lika-0.1%, iphesenti elincane le-niobium lithuthukisa amandla ensimbi. Ukuzinza kwezinga lokushisa kwama-superalloys aqukethe i-niobium kubalulekile ekusetshenzisweni kwawo ezinjinini zejethi nezamarokhethi.
I-Niobium isetshenziswa ezintweni ezihlukahlukene ze-superconducting. Lawa ma-alloys amakhulu, nawo aqukethe i-titanium ne-tin, asetshenziswa kakhulu kozibuthe abakhulu bezithwebuli ze-MRI. Ezinye izinhlelo zokusebenza ze-niobium zifaka ukushisela, izimboni zenuzi, i-electronics, optics, numismatics, nobucwebe. Kuzicelo ezimbili zokugcina, ubuthi obuphansi kanye ne-iridescence ekhiqizwa i-anodization yizinto ezifiseleka kakhulu. I-Niobium ithathwa njengento ebaluleke kakhulu kwezobuchwepheshe.
Izici zomzimba
I-Niobium iyinsimbi ecwebezelayo, empunga, edonsayo, ene-paramagnetic eqoqweni lesi-5 letafula lezikhathi (bheka ithebula), enokucushwa kwe-electron kumagobolondo angaphandle atypical eqembu lesi-5. (Lokhu kungabonwa endaweni ye-ruthenium (44), i-rhodium (45), ne-palladium (46).
Nakuba kucatshangwa ukuthi inesakhiwo sekristalu eyi-cubic egxile emzimbeni ukusuka kuqanda ukuya endaweni yayo yokuncibilika, izilinganiso zokulungiswa okuphezulu kokunwetshwa okushisayo okuhambisana nezimbazo ezintathu zekristalu zembula ama-anisotropies angahambisani nesakhiwo se-cubic.[28] Ngakho-ke, ucwaningo olwengeziwe nokutholakala kule ndawo kulindeleke.
I-Niobium iba yi-superconductor emazingeni okushisa e-cryogenic. Engcindezini yomoya, inezinga lokushisa eliphakeme kakhulu elibucayi lama-elemental superconductors ku-9.2 K. I-Niobium inokujula kokungena kazibuthe okukhulu kakhulu kwanoma iyiphi i-elementi. Ngaphezu kwalokho, ingenye yezinto ezintathu eziyinhloko zohlobo lwe-II superconductors, kanye ne-vanadium ne-technetium. Izakhiwo ze-superconductive zincike kakhulu ekuhlanzekeni kwensimbi ye-niobium.
Uma ihlanzekile kakhulu, ithambile ngokuqhathaniswa futhi i-ductile, kodwa ukungcola kwenza kube nzima.
Insimbi ine-cross-section yokubamba okuphansi kwama-neutron ashisayo; ngaleyo ndlela isetshenziswa ezimbonini zenuzi lapho izakhiwo ze-neutron ezibonisa ngale zifunwa.
Izici zamakhemikhali
Insimbi iba nombala oluhlaza okwesibhakabhaka lapho ibekwe emoyeni ekamelweni lokushisa isikhathi eside. Naphezu kwendawo ephezulu yokuncibilika kufomu lokuqala (2,468 °C), inomthamo ophansi kunezinye izinsimbi eziphikisayo. Ngaphezu kwalokho, ayikwazi ukumelana nokugqwala, ikhombisa izakhiwo ze-superconductivity, futhi yakha izendlalelo ze-dielectric oxide.
I-Niobium i-electropositive kancane futhi ihlangene kakhulu kuneyandulelayo kuthebula le-periodic, i-zirconium, kuyilapho icishe ifane ngosayizi nama-athomu e-tantalum asindayo, ngenxa yokufinyela kwe-lanthanide. Ngenxa yalokho, izakhiwo zamakhemikhali e-niobium zifana kakhulu nalezo ze-tantalum, ezivela ngokuqondile ngaphansi kwe-niobium kuthebula le-periodic. Nakuba ukumelana nokugqwala kwayo kungavelele njengalokho kwe-tantalum, intengo ephansi nokutholakala okukhulu kwenza i-niobium ithandeke ekusetshenzisweni okungadingeki kangako, njengemigqa ye-vat ezitshalweni zamakhemikhali.